Office: Pfaffenwaldring 55, 0.814
Phone: +49 711 685
Email: wael.barakat@itc.uni-stuttgart.de

CRC1333 – Project B05

Copper hydrides are widely used catalyst in different reactions such as CO2 hydrogenation, hydrosilylation, and hydroboration. For that purpose, we are trying to synthesize a mononuclear Cu-H complexes in Lewis acidic mesoporous materials such as covalent organic frameworks (COFs) or mesoporous metal oxides and investigate the effect of confinement on activity and selectivity for gas-phase CO2 hydrogenation.

Immobilized Ruthenium Hydride Complexes for CO2 Reduction under Confinement Effects.

Office: Pfaffenwaldring 55, 1.840
Phone: +49 711 685 64306
Email: michael.benz@itc.uni-stuttgart.de 

Heterogeneous flow-reactor testing on the reduction of CO₂ to Methanol with special focus on spillover and interactions of the reducible metal oxide supports. Investigations on isolated intermediates by molecular models of hydrogen spillover and reduction tests with CO2 in batch reactions.

Office: Pfaffenwaldring 55, 1.840
Phone: +49 711 685 64309
Email: erik.wimmer@itc.uni-stuttgart.de 

CRC1333 – Project B08 – Probing Confinement Enhanced Precatalyst Association in Pd Catalyzed Enyne Cycloisomerizations by Advanced NMR Spectroscopy

We are investigating and synthesizing platinum and palladium hydrides for enhanced catalytic reactions, particularly (enantio-)selective enyne cycloisomerization. This investigation aims to enhance reactions through innovative catalyst immobilization, fostering deeper mechanistic understanding.

Office: Pfaffenwaldring 55, 1.840
Phone: +49 711 60048
Email: osman.bunjaku@itc.uni-stuttgart.de 

Surface chemistry on catalysts is a complex process in which many parameters influence the kinetics and selectivity. By using hydride complexes, we aim to model hydrogen spillover from known catalyst systems to gain a deeper understanding and improve these systems.

Office: Pfaffenwaldring 55, 7.563
Phone: +49 711 64306
Email: mustafa.turan@itc.uni-stuttgart.de 

Turning lignin into fuel. Studying the mechanisms of hydrodeoxygenation with the help of hydrogen-spillover.

Office: Pfaffenwaldring 55, 1.840
Phone: +49 711 60067
Email: zeki.beydeda@itc.uni-stuttgart.de

Immobilized Pt/Sn based catalysts for Hydroformylation reactions.

Office: Pfaffenwaldring 55, 1.840
Phone: +49 711 685 64069
Email: sarah.maier[{at}]itc.uni-stuttgart.de

Cu-catalyzed atom transfer radical addition reactions (ATRA) enable the versatile functionalization of alkenes and the simple synthesis of functionalized lactones and lactams. However, their disadvantage is that they often require high catalyst loadings, which makes them unsuitable for industrial processes. Polymerization reactions are a special case in which tailor-made polymers can be produced with low catalyst loading.
Since the redox process between Cu(I) and Cu(II) is reversible, it is possible to regenerate deactivated catalysts after the reaction if they can be separated intact and cleanly from the reaction mixture. This is made possible by immobilized catalysts, which are therefore an important tool for making ATRA reactions more sustainable and efficient